RICERCHE FINANZIATE
Ricerche finanziate come responsabile:
finanziamento di ateno (ex 60%) 2006 e 2007
Finanziamenti come componente:
PRIN 1999, 2001, 2003
finanziamento di ateno (ex 60%) dal 1985 al 2005
finanziamento di ateno (ex 60%) 2012
finanziamenti a carattere nazionale (ex 40%)
finanziamenti del CNR
ASSOCIAZIONI SCIENTIFICHE
Componente della Società Chimica italiana
Componente della divisione di Chimica Oreganica della SCI
Componente del Gruppo interdivisionale di fotochimica della SCI
Componente della European Photochemistry Association (EPA)
Componente del Consorzio Interuniversitario Nazionale per la Scienza e la Tecnologia dei Materiali
Componente dell’Advisory Board dell’Istituto Euro Mediterraneo di Scienza e Tecnologie
PUBBLICAZIONE
Elenco delle Pubblicazioni
Prof. Silvestre Buscemi
1) Linear Free Energy ortho-Correlations in the Thiophene Series. Part IX. Kinetics of Esterification with
Diazodiphenylmethane of Some 3-, 4-, and 5-Substituted Thiophene-2-carboxylic Acids in Methanol.
R. Noto, S. Buscemi, G. Consiglio, and D. Spinelli.
J. Heterocycl. Chem., 18, 735 (1981).
2) Lead Tetraacetate Oxidation of Phenylhydrazones of 3-Benzoylazoles. Synthesis of Azoacetates and Their
Conversion into Indazoles.
N. Vivona, V. Frenna, S. Buscemi, and M. Condò.
J. Heterocycl. Chem., 22, 29 (1985).
3) Heterocyclic Rearrangements. N,N-Diphenylhydrazones, Oximes and O-Methyloximes of 3-Benzoyl-5-
phenyl-1,2,4-oxadiazole.
N. Vivona, V. Frenna, S. Buscemi, and M. Ruccia.
J. Heterocycl. Chem., 22, 97 (1985).
4) Heterocyclic Rearrangements. Rearrangement of the Oximes of Some 3-Acyl-1,2,4-oxadiazoles into 1,2,5-
Oxadiazoles: A Revision.
N. Vivona, S. Buscemi, V. Frenna, M. Ruccia, and M. Condò.
J. Chem. Research, (S),190 (1985), (M), 2184 (1985).
5) Heterocyclic Rearrangements. Rearrangement of N-(1,2,4-Oxadiazol-3-yl)-b-enamino Ketones into Pyrimidine
N-Oxides.
N. Vivona, S. Buscemi, V. Frenna, and M. Ruccia.
J. Chem. Soc., Perkin Trans. 1, 17 (1986).
6) Heterocyclic Rearrangements. Synthesis of 1,2,4-Oxadiazolo[2,3-a] pyrimidinium Systems and Their Ring
Opening into Pyrimidine N-Oxides.
S. Buscemi, G. Macaluso, V. Frenna, and N. Vivona.
J. Heterocycl. Chem., 23, 1175 (1986).
7) Heterocyclic Rearrangements. Rearrangement of 1,2,4-Oxadiazoles, Isoxazoles, and 1,2,5-Oxadiazoles
Involving a Carbethoxythiourea NCS Sequence.
G. Macaluso, G. Cusmano, S. Buscemi, V. Frenna, N. Vivona, and M. Ruccia.
Heterocycles, 24, 3433 (1986).
8) On the Configuration and the Conformation of 2-Acylindazole Aryl-hydrazones.
G. Cusmano, G. Macaluso, W. Hinz, and S. Buscemi.
Heterocycles, 26, 1283 (1987).
9) Studies on Decarboxylation Reactions. Part 5. Micellar Catalysis and Mixed Solvents Effects on the
Decarboxylation of Some N-Alkyl- or N-Aryl-substituted 5-Amino-1,3,4-oxadiazole-2-carboxylic Acids.
R. Noto, S. Buscemi, G. Werber, and D. Spinelli.
J. Heterocycl. Chem., 24, 1449 (1987).
10) Photochemical Behaviour of Some 1,2,4-Oxadiazole Derivatives.
S. Buscemi, M. G. Cicero, N. Vivona, and T. Caronna.
J. Chem. Soc., Perkin Trans. 1, 1313 (1988).
11) Heterocyclic Photorearrangements. Photochemical Behaviour of Some 3,5-Disubstituted 1,2,4-Oxadiazoles in
Methanol at 254 nm.
S. Buscemi, M.G. Cicero, N. Vivona, and T. Caronna.
J. Heterocycl. Chem., 25, 931 (1988).
12) Mononuclear Heterocyclic Rearrangements. Part 15. Kinetic Study of the Amine-catalysed Rearrangement of
Some Z-Arylhydrazones of 3-Benzoyl-5-phenylisoxazole into 2-Aryl-4-phenacyl-5-phenyl-1,2,3-triazoles in Acetonitrile
and in Benzene.
V. Frenna , S. Buscemi, and C. Arnone.
J. Chem. Soc., Perkin Trans 2, 1683 (1988).
13) Heterocyclic Photorearrangements. Photoinduced Rearrangements of 1,2,4-Oxadiazoles Substituted by an
XYZ Side Chain Sequence.
S. Buscemi and N. Vivona .
J. Heterocycl. Chem, 25, 1551 (1988).
14) Heterocyclic Photorearrangements. Photoinduced Rearrangements of some 3-Aroylamino-5-methyl-1,2,4-
oxadiazoles.
S. Buscemi and N. Vivona.
Heterocycles, 29, 737 (1989).
15) Heterocyclic Photorearrangements. Photochemical Behaviour of some 3-Acetylamino-5-aryl-1,2,4-
oxadiazoles. A Photoinduced Iso-heterocyclic Rearrangement.
S. Buscemi, G. Macaluso, and N. Vivona.
Heterocycles, 29, 1301 (1989).
16) Cyclization Reactions of Arylhydrazone Adducts. Synthesis of 1-Aryl-1H-1,2,4-Triazolo[4,3-b ] indazoles.
G. Cusmano, G. Macaluso, M. Gruttadauria, and S. Buscemi.
Heterocycles, 29, 2149 (1989).
17) A Kinetic Study on the Base-catalysed E
The
resource
of this
report
item is
not
reachable.Z Isomerization of Some Arylhydrazones of 3-Benzoyl-5-
phenyl-1,2,4-oxadiazole: Effect of the Substituents in the Arylhydrazone Moiety.
V. Frenna , S. Buscemi, D. Spinelli, and G. Consiglio.
J. Chem. Soc., Perkin Trans 2, 215 (1990).
18) Heterocyclic Photorearrangements. Photoinduced Rearrangement of 3-Styryl-1,2,4-Oxadiazoles.
S. Buscemi, G. Cusmano, and M. Gruttadauria.
J. Heterocycl. Chem, 27, 861 (1990).
19) A Synthesis of 1,2,4-Triazolo[1,5-f]phenanthridines by Rearrangements of 1,2,5-Oxadiazoles Involving an
NCN Sequence with the Imine Nitrogen in an Aromatic Heterocyclic Ring.
G. Cusmano, G. Macaluso, M. Gruttadauria, and S. Buscemi.
Heterocycles, 31, 869 (1990).
20) Heterocyclic Photorearrangements. Some Investigations on the Photochemical Behaviour of 3-
Acylamino-1,2,4-oxadiazoles. Synthesis of the Quinazolin-4-one System.
S. Buscemi and N. Vivona.
J. Chem. Soc., Perkin Trans 2, 187 (1991).
21) Heterocyclic Rearrangements. – A Semiempirical Study of a Degenerate Rearrangement in the 1,2,4-
Oxadiazole Series.
G. La Manna, S. Buscemi, V. Frenna, N. Vivona, and D. Spinelli.
Heterocycles, 32, 1547 (1991).
22) Heterocyclic Rearrangements. – The Rearrangement of 3-Aroylaminoisoxazoles into 2-aroylaminooxazoles.
S. Buscemi, V. Frenna, and N. Vivona.
Heterocycles, 32, 1765 (1991).
23) Photochemical Cyclization of some Aldehyde Thiosemicarbazones.
M. Gruttadauria, F. Buccheri, S. Buscemi, G. Cusmano, R. Noto,
and G. Werber.
J. Heterocycl. Chem, 29, 233 (1992).
24) Photochemical Behaviour of 1,2,5-Oxadiazoles. Irradiation of some 3-Acylamino-1,2,5-oxaziazoles in the
presence of nucleophiles.
S. Buscemi, V. Frenna, T. Caronna, and N. Vivona.
Heterocycles, 34, 2313 (1992).
25) Copper(II)-catalyzed Mononuclear Rearrangements: the Behaviour of Arylhydrazones of some 3-
Benzoylazoles in the Presence of Copper(II) acetate.
S. Buscemi, V. Frenna, N. Vivona, and D. Spinelli.
J. Chem. Soc., Perkin Trans 1, 2491 (1993)
26) Ring Transformations of Five-Membered Heterocycles.
N. Vivona, S. Buscemi, V. Frenna, and G. Cusmano.
Adv. Heterocycl. Chem., (A. R. Katritzky Ed.), 56, 49 (1993).
27) Molecularr Rearrangements in Heterocyclic Synthesis. A Generalized Synthesis of 1,2,4-Thiadiazoles from 3-
Acylamino-1-oxa-2-azoles.
S. Buscemi and N. Vivona.
Heterocycles, 38, 2423 (1994).
28) Studies on Azole-to-Azole Interconversions. Substituent Effects on the Ring-degenerate Equilibration between
3-Aroylamino-5-methyl-1,2,4-oxadiazoles and 3-acetylamino-5-aryl-1,2,4-oxadiazoles.
S. Buscemi, V. Frenna, N. Vivona, G. Petrillo, and D. Spinelli.
Tetrahedron, 51, 5133 (1995).
29) Photoinduced Molecular Rearrangements. Some Investigations of the Photochemical Behaviour of 3-
(Acylamino)-1,2,5-oxadiazoles (Furazans).
S. Buscemi, N. Vivona, and T. Caronna.
J. Org. Chem., 60, 4096 (1995).
30) A Generalized and Efficent Synthesis of 3-Amino-, 3-(N-Alkylamino)-, 3-(N,N-Dialkylamino)-5-alkyl-1,2,4-
oxadiazoles by Irradiation of 3-Alkanoylamino-4-phenyl-1,2,5-oxadiazoles (Furazans).
S. Buscemi, N. Vivona, and T. Caronna.
Synthesis., 917 (1995).
31) Photoinduced Molecular Rearrangements of O-N Bond-containing Five-membered Heterocycles. An Assay for
1,2,4- and 1,2,5-oxadiazoles.
N. Vivona and S. Buscemi.
Heterocycles, 41, 2095 (1995).
32) Photoinduced Molecular Rearrangements. The Photochemistry of Some 1,2,4-Oxadiazoles in the Presence of
Nitrogen Nucleophiles. Formation of 1,2,4-Triazoles, Indazoles, and Benzimidazoles.
S. Buscemi, N. Vivona, and T. Caronna.
J. Org. Chem., 61, 8397 (1996).
33) Photoinduced Molecular Rearrangements. The Photochemistry of 1,2,4-Oxadiazoles in the Presence of
Sulphur Nucleophiles. Synthesis of 1,2,4-Thiadiazoles.
N. Vivona, S. Buscemi, S. Asta, and T. Caronna.
Tetrahedron, 53, 12629 (1997).
34) Theoretical Study of Degenerate Boulton-Katritzky Rearrangements. Semiempirical and ab Initio Procedures.
G. La Manna, S. Buscemi, and N. Vivona.
J. Mol. Struct. (Theochem), 452, 67, (1998).
35) The Photochemistry of 2-Diazo- and 3-Diazopyrroles
S. Buscemi, A. Pace, G. Cirrincione, and P. Diana.
Heterocycles, 51, 1631, (1999).
36) New Biodegradable hydrogels Based on a Photocrosslinkable Modified Polyaspartamide: Synthesis and
Characterizations.
G. Giammona, G. Pitarresi, G. Cavallaro, S Buscemi, and F. Saiano.
Biochimica and Biophysica Acta, 1428, 29 (1999).
37) Photoinduced Single Electron Transfer on 5-Aryl-1,2,4-oxadiazoles: Some Mechanistic Investigations in
the Synthesis of Quinazolin-4-ones.
S. Buscemi, A. Pace, N. Vivona, T. Caronna, and A. Galia.
J. Org. Chem., 64, 7028 (1999).
38) Sensitized Photoreduction of Nitrosoazoles on Titanium Dioxide.
A. Pace, S. Buscemi, N. Vivona, and T. Caronna.
Heterocycles, 53, 183, (2000).
39) Photocyclization Reaction of Some 2-Methyl-4-phenyl- Substituted Aldehyde Thiosemicarbazones.
Mechanistic Aspects.
S. Buscemi and M. Gruttadauria.
Tetrahedron, 56, 999, (2000).
40)Fluoro Heterocycles. A Photochemical Methodology for the Synthesis of 3-Amino- and 3-(N-alkylamino)-5-
perfluoroalkyl-1,2,4-oxadiazoles.
S. Buscemi, A. Pace, and N. Vivona .
Tetrahedron Lett., 41, 7977, (2000).
41) Ultraviolet-Induced Cross-linking of a Functionalized Polyaspartamide Carrying Ester Groups.
G: Pitarresi, E. F. Craparo, B. Carlisi, G. Giammona, and S. Buscemi
J. Bioact. Compat. Polym., 16, 98, (2001).
42) New Biodegradabile Hydrogels Based on a Photo-cross-linkable Polyaspartamide and poly(ethylene glycol)
derivatives. Release studies of an Anticancer Drug.
G. Giammona, G. Pitarresi, E. F. Craparo, G. Cavallaro, and S. Buscemi.
Colloid. Polym. Sci. , 279, 771, (2001).
43) Photoinduced Molecular Rearrangements. Some Comments on the Ring-Photoisomerization of 1,2,4-
Oxadiazoles into 1,3,4-Oxadiazoles.
S. Buscemi, A. Pace, N. Vivona, and T. Caronna.
J. Heterocycl. Chem, 38, 777 (2001).
44) Fluorinated Heterocyclic Compounds. A Photochemical Synthesis of 3-Amino-5-perfluoroaryl-1,2,4-
oxadiazoles.
S. Buscemi, A. Pace, R. Calabrese, N. Vivona, and P. Metrangolo.
Tetrahedron, 57, 5865, (2001).
45) On the Synthesis and Reactivity of the Z-2,4-Dinitrophenylhydrazone of 5-Amino-3-benzoyl-1,2,4-
oxadiazole.
B. Cosimelli, S. Guarnelli, D. Spinelli, S. Buscemi, V. Frenna, and G. Macaluso.
J. Org. Chem., 66, 6124 (2001).
46) Photoinduced Functionalization of C-20 Methyl Group of the Nor-diterpene Atractyligenin.
S. Buscemi, S. Rosselli, M. Bruno, N. Vivona, and F. Piozzi.
Tetrahedron Lett., 42, 8289, (2001).
47) An Analysis of 1H, 13C and 15N NMR Substituent Chemical Shifts in para- and meta-Substituted (Z)-
Phenylhydrazones of 3-Benzoyl-5-phenyl-1,2,4-oxadiazoles.
E. Mezzina, D. Spinelli, L: Lamartina, S. Buscemi, V. Frenna, and G. Macaluso.
E. J. Org. Chem, 203 (2002).
48) Studies on Azole-to-Azole Interconversion. – An Interesting Case of Absence of a “Primary Steric Effect” in
the Ring-degenerate Equilibration between ortho-Substituted 3-Aroylamino-5-methyl-1,2,4-oxadiazoles and 3-
Acetylamino-5-aryl-1,2,4-oxadiazoles in Methanol.
S. Buscemi, V. Frenna, A. Pace, N. Vivona, B. Cosimelli, and D. Spinelli.
E .J. Org. Chem, 1417 (2002).
49) A Generalized Synthesis of 3-Amino-5-aryl-, 3-Amino-5-polyfluorophenyl-, and 3-Amino-5-alkyl-1,2,4-
oxadiazoles through Ring-degenerate Rearrangements.
S. Buscemi, A. Pace, V. Frenna, and N. Vivona.
Heterocycles, 57, 811 (2002).
50) Competing Ring-photoisomerization Pathways in the 1,2,4-Oxadiazole Series. An Unprecedented Ringdegenerate
Photoisomerization.
S. Buscemi, A. Pace, I. Pibiri, and N. Vivona.
J. Org. Chem., 67, 6253 (2002).
51) Fluorinated Heterocyclic Compounds. Synthesis of 5-Amino-, 5-N-Alkylamino-, 5-N,N-Dialkylamino-3-
perfluoroheptyl-1,2,4-oxadiazoles.
S. Buscemi, A. Pace, I. Pibiri, and N. Vivona.
Heterocycles, 57, 1891 (2002).
52) Photoinduced Functionalization of Diterpenes. Transformation of the C-20 Methyl of Atractyligenin into a
Carbomethoxymethyl or Carbamoylmethyl group.
S. Buscemi, S. Rosselli, M. Bruno, N. Vivona, and F. Piozzi.
J. Photochemistry and Photobiology A: Chemistry, 155, 145 (2003).
53) Fluorinated Heterocyclic Compounds. An Expedient Route to 5-Perfluoroalkyl-1,2,4-triazoles via an Unusual
Hydrazinolysis of 5-Perfluoroalkyl-1,2,4-oxadiazoles: First Examples of an ANRORC-like Reaction in the 1,2,4-
Oxadiazole Derivatives.
S. Buscemi, A. Pace, I. Pibiri, N. Vivona, and D. Spinelli.
J. Org. Chem., 68, 605 (2003).
54) Fluorinated Heterocyclic Compounds. An Assay on the Photochemistry of Some Fluorinated 1-Oxa-2-azoles:
An Expedient Route to Fluorinated Heterocycles
S. Buscemi, A. Pace, I. Pibiri, N. Vivona and T. Caronna.
J. Fluorine Chem., 125, 165 (2004)
55) Photoinduced Functionalization of Diterpenes: Photochemical Behaviour of Grandiflorolic acid in Methanol and
Acetonitrile.
S. Buscemi, S. Rosselli, M. Bruno, L. Scaglioni, N. Vivona, and F. Piozzi.
J. Photochemistry and Photobiology A: Chemistry, 162, 381 (2004).
56) Fluorinated Heterocyclic Compounds.The First Example of an IrreversibleRing-Degenerate
Rearrangement on Five-Membered Heterocycles by Attack of an External Bidentate Nucleophile.
S. Buscemi, A. Pace, I. Pibiri, N. Vivona, C. Z. Lanza and D. Spinelli.
Eur. J. Org. Chem., 974 (2004).
57) Theoretical study of photoinduced ring-isomerization in the1,2,4-oxadiazole series
S. Buscemi, M. D’Auria, A. Pace, I. Pibiri, and N. Vivona.
Tetrahedron, 60, 3243, (2004).
58) The Photochemistry of Fluorinated Heterocyclic Compounds. An Expedient Route for the Synthesis of
Fluorinated 1,3,4-Oxadiazoles and 1,2,4-Triazoles.
A. Pace, I. Pibiri, S. Buscemi ,N. Vivona, and L. Malpezzi
J. Org. Chem., 69, 4108 (2004).
59) Fluorinated Heterocyclic CompoundS. A Photochemical Approach to a Synthesis of Fluorinated Quinazolin-4-
ones
S. Buscemi, A. Pace, A. Palumbo Piccionello, I. Pibiri, and N. Vivona.
Heterocycles, 63, 1619 (2004).
60) Molecular Rearrangements of 1-oxa-2-azoles as an Expedient Route to Fluorinated Heterociclic Compounds.
A. Pace, I. Pibiri, S. Buscemi, and N. Vivona
Heterocycles, 63, 2627 (2004).
61) Fluorinated Heterocyclic Compounds A Photocemical Approach to a Synthesis of Polyfluoroaryl-1,2,4-
Triazoles
S. Buscemi, A. Pace, A. Palumbo Piccionello, I. Pibiri, and N. Vivona.
Heterocycles, 65, 387 (2005).
62) Heterocyclic Rearrangements in Constrained Media. A Zeolite-Directed Photorearrangement of 1,2,4-
Oxadiazoles
A. Pace, S. Buscemi, and N. Vivona
J. Org. Chem., 70, 2322 (2005).
63) Fluorinated Heterocyclic Compounds. An Effective Strategy for the Synthesis of Fluorinated Z-Oximes of 3-
Perfluoroalkyl-6-phenyl-2H-1,2,4-triazin-5-ones via a Ring-Enlargement Reaction of 3-Benzoyl-5-perfluoroalkyl-1,2,4-
oxadiazoles and Hydrazine
S. Buscemi, A. Pace, A. Palumbo Piccionello, G. Macaluso, N. Vivona, D. Spinelli and G. Giorgi.
J. Org. Chem., 70, 3288 (2005).
64) A Survey on the Synthesis of Fluorinated Heteroaromatic Compounds. Part 1: Five-membered Rings with More than
Two Heteroatoms.
A. Pace, S. Buscemi, and N. Vivona
Org. Prep. Proc. Int., 37, 447 (2005).
65) One-Pot Synthesis of Fluorinated 2-Amino-Pyrimidine-N-Oxides. Competing Pathways in the Four-atom Sidechain
Rearrangements of 1,2,4-Oxadiazoles.
S. Buscemi, A. Pace, A. Palumbo Piccionello, N. Vivona and M. Pani.
Tetrahedron, 62, 1158, (2006)
66) Designing Fluorous Domains. Synthesis of a Series of Pyridinium Salts Bearing a Perfluoroalkylated Azole
Moiety
I. Pibiri, A. Pace, S. Buscemi, N. Vivona, and L. Malpezzi.
Heterocycles, 68,307 (2006).
67) The Photochemistry of 1,2,4-Oxadiazoles. A DFT Study on Photoinduced Competitive Rearrangements of 3-
Amino- and 3-N-Methylamino-5-perfluoroalkyl-1,2,4-oxadiazoles.
A. Pace, S. Buscemi, N. Vivona, A. Silvestri, and G. Barone
J. Org. Chem., 71, 2740 (2006).
68) Photochemical Reactivity of 6α-Hydroxy, 7-Keto NeoclerodaneDiterpenoids.
M. Bruno, S. Buscemi, S. Rosselli and L. Scaglioni
J. Photochemistry and Photobiology A: Chemistry, 180, 54 (2006).
69) Synthesis of Fluorinated Indazoles through ANRORC-like Rearrangement of 1,2,4-Oxadiazoles with
Hydrazine.
A. Palumbo Piccionello, A. Pace, I. Pibiri, S. Buscemi and N. Vivona
Tetrahedron, 62, 8792, (2006).
70) Five-to-Six Membered Ring-rearrangements in the Reaction of 5-Perfluoroalkyl-1,2,4-oxadiazoles with
Hydrazine and Methylhydrazine.
S. Buscemi, A. Pace, A. Palumbo Piccionello, I. Pibiri, N. Vivona, G. Giorgi, A. Mazzanti and D. Spinelli.
J. Org. Chem., 71, 8106(2006).
71) Synthesis of fluorinated first generation starburst molecules containing a triethanolamine core and 1,2,4-
oxadiazoles.
S. Buscemi, A. Pace, A. Palumbo Piccionello and N. Vivona.
J. Fluorine Chem., 127, 1601 (2006)
72) Lower Rim Arylation of Calix[n]arenes withExtended Perfluorinated Domains
S. Buscemi, A. Pace, A. Palumbo Piccionello, S. Pappalardo, D, Garozzo, T. Pilati, G. Gattuso, A. Pappalardo, I.
Pisagatti and M. F. Parisie.
Tetrahedron Letters , 47, 9049, (2006).
73) Synthesis and Characterization of a Series of Alkyl oxadiazolylpyridinium Salts as Perspective Ionic Liquids.
I. Pibiri, A. Pace, A. Palumbo Piccionello, P. Pierro and S. Buscemi.
Heterocycles, 68,2653 (2006).
74) Study on the Thermotropic Properties of Highly Fluorinated 1,2,4-Oxadiazolyl-pyridinium Salts and their
Perspective Applications as Ionic Liquid Crystals
F. Lo Celso,, I. Pibiri, A. Triolo, R. Triolo, A. Pace, S. Buscemi, and N. Vivona
J. Mater. Chem., 17, 1201 (2007).
75) Photooxidations of Alkenes in Fluorinated Constrained Media. Fluoro-organically Modified NaY as Improved
Reactors for Singlet Oxygen “Ene” Reactions.
A. Pace, P. Pierro, S. Buscemi, N. Vivona, and E. L. Clennan.
J. Org. Chem., 72, 2644 (2007).
76 The synthesis of fluorinated heteroaromatic compounds. Part 2. Five-membered rings with two
heteroatoms. A review
A. Pace, S. Buscemi, and N. Vivona
Org. Prep. Proc. Int., 39, 1 (2007).
77) Fluoropolymer Based on a Polyaspartamide containing 1,2,4-Oxadiazole Units: A Potential Artificial Oxygen
(O2) Carrier
D. Mandracchia, A. Palumbo Piccionello, G. Pitarresi, A. Pace, S. Buscemi, G. Giammona
Macromol. Biosci., 7, 836, (2007)
78) On the Photochemistry of Some 1,2,4-Oxadiazoles in the Presence of 2,3-Dimethyl-2-butene. Synthesis of NImidoyl-aziridines.
A. Palumbo Piccionello, I. Pibiri, A. Pace, R. A. Raccuglia, S. Buscemi, N. Vivona, and G. Giorgi.
Heterocycles, 71, 1529 (2007).
79) Characcharacterization of Isomeric 1,2,4-oxadiazolyl-N-Methylpyridinium Salts by ESI-MS/MS.
G. Avellone, D. Bongiorno, S. Buscemi, L. Ceraulo, S. Indelicato, A. Pace, I.Pibiri, N. Vivona
Eur. J. Mass Spectrom., 13, 199 ( 2007).
80) Experimental and DFT Studies on Competitive Heterocyclic Rearrangements. Part 2:1 A One-Atom SideChain
versus the Classic Three-Atom Side-Chain (Boulton-Katritzky) Ring. Rearrangement of 3-Acylamino-1,2,4-
oxadiazoles‡
A. Pace, I. Pibiri, A.Palumbo Piccionello, S. Buscemi, N. Vivona, and G. Barone.
J. Org. Chem., 72, 7656 (2007).
81) Hydration/elimination reactions of trapped protonated fluoroalkyl triazines.
G. Giorgi, A. Palumbo Piccionello, A. Pace, S. Buscemi.
J. Mass Spectrom, 43, 265 (2008)
82) Synthesis of Trifluoromethylated 2-Benzoyl- and 3-aminoimidazoles from Ring Rearrangement of 1,2,4-
Oxadiazole Derivative.
A. Palumbo Piccionello, A. Pace, S. Buscemi, N. Vivona, and M. Pani.
Tetrahedron, 64, 4004 (2008).
83) Effect of Protonation and Deprotonation on the Gas-Phase Reactivity of Fluorinated1,2,4-Triazines
G. Giorgi, A. Palumbo Piccionello, A. Pace, S. Buscemi.
J Am Soc Mass Spectrom, 19, 686 (2008)
84) Fluorinated derivatives of a polyaspartamide bearing polyethylene glycol chains as oxygen carriers
G. Pitarresi, A. Palumbo Piccionello, R. Calabrese, A. Pace, S. Buscemi, G. Giammona
J. of Fluorine Chemistry 129, 1096 (2008)
85) On the reaction of some 5-polyfluoroaryl-1,2,4-oxadiazoles with methylhydrazine: synthesis of fluorinated
indazoles
A. Palumbo Piccionello, A. Pace, P. Pierro, I. Pibiri, S. Buscemi, N Vivona
Tetrahedron, 65, 119 (2009).
86) Experimental and DFT Studies on Competitive Heterocyclic Rearrangements. A Cascade Isoxazole-1,2,4-
Oxadiazole-Oxazole Rearrangement‡
A.Pace, P. Pierro, S. Buscemi, N. Vivona, G. Barone
J. Org. Chem., 74, 351 (2009).
87) Synthesis of fluorinated 1,2,4-oxadiazin-6-ones through ANRORC rearrangement of 1,2,4-oxadiazoles
A. Palumbo Piccionello, A. Pace, S. Buscemi, N. Vivona a, G. Giorgi b
Tetrahedron Letters , 50, 1472 (2009).
88) Solvent dependent photochemical reactivity of 3-allyloxy-1,2,4-oxadiazoles
A. Palumbo Piccionello, A. Pace, I. Pibiri, S. Buscemi.
ARKIVOC 156 (2009)
89) Gas phase behavior of radical cations of perfluoroalkyl-1,2,4-triazines: an experimental and theoretical study
G. Giorgi, A Palumbo Piccionello, A Pace, S. Buscemi.
Journal of Mass Spectrometry, 44, 1369 (2009).
90) 1,2,4-Oxadiazole Rearrangements Involving an NNC Side-Chain Sequence.
A. Palumbo Piccionello, A. Pace, S. Buscemi, N. Vivona.
Organic Letters, 11(17), 4018 (2009).
91) On the structure of 3-acetylamino-5-methyl- 1,2,4-oxadiazole and on the fully degenerate rearrangements
(FDR) of its anion: a stimulating comparison between the results of ‘in-silicon chemistry’ and ‘laboratory chemistry’.
A. Mugnoli, G. A. Barone, S. Buscemi, C. Z. Lanza, A. Pace, M. Pani, D. Spinelli,
Journal of Physical Organic Chemistry, 22, 1086. (2009).
92) An ANRORC approach to the synthesis of perfluoroalkylated 1,2,4-triazole-carboxamides.
A. Palumbo Piccionello, A. Pace, S. Buscemi, N. Vivona.
Arkivoc, 235 (2009)..
93) Extended Investigation of the Aqueous Self-Assembling Behavior of a Newly Designed Fluorinated Surfactant.
S. Buscemi, G. Lazzara, S. Milioto, A. Palumbo Piccionello
Langmuir, 13368 (2009).
94) A recent portrait of bioactive triazoles.
I. Pibiri, S. Buscemi.
Current Bioactive Compounds, 6, 208 (2010).
95) Exploiting the CNC Side Chain in Heterocyclic Rearrangements: Synthesis of 4(5)-Acylamino-imidazoles.
A. Palumbo Piccionello, S. Buscemi, N. Vivona, A. Pace.
Organic Letters, 12, 3491 (2010).
96) Fluorescent Hg2+ Sensors: Synthesis and Evaluation of a Tren-Based Starburst Molecule Containing
Fluorinated 1,2,4-Oxadiazoles.
I. PibiriA, Palumbo Piccionello, A. Calabrese, S. Buscemi, N. Vivona, A. Pace.
European Journal of Organic Chemistry, 4549 (2010).
97) Synthesis, characterization, cellular uptake and interaction with native DNA of a bis(pyridyl)-1,2,4-oxadiazole
copper(II) complex.
A. Terenzi, G. Barone, A. Palumbo Piccionello, G. Giorgi, A. Guarcello, P. Portanova, G. Calvaruso, S.
Buscemi, N. Vivona, A. Pace.
Dalton Transactions, 39, 9140 (2010).
98) Synthesis of Amino-1,2,4-triazoles by Reductive ANRORC Rearrangements of 1,2,4-Oxadiazoles.
A. Palumbo Piccionello, A. Guarcello, S. Buscemi, N. Vivona, A. Pace.
Journal of Organic Chemistry, 75, 8724. (2010).
99) Synthesis of 4(5)-phenacyl-imidazoles from isoxazole side-chain rearrangements.
A. Martorana, A. Palumbo Piccionello, S. Buscemi, G. Giorgi, A. Pace,
Organic & Biomolecular Chemistry, 9(9), 491 (2011).
100) Tandem reaction of 1,2,4-oxadiazoles with allylamines.
A. Piccionello Palumbo; A. Pace; S. Buscemi.
Organic Letters, 13 (17) 4749 (2011).
101) Synthesis of fluorinated oxadiazoles with gelation and oxygen storage ability.
A. Piccionello Palumbo; A: Guarcello; A. Calabrese; I. Pibiri; A. Pace; S. Buscemi
Organic & Biomolecular Chemistry, 10 (15) 3044 (2012).
102) Fluorinated and pegylated polyaspartamide
derivatives to increase solubility and efficacy of Flutamide
A. Piccionello Palumbo; G. Pitarresi; A. Pace; D. Triolo; P. Picone; S. Buscemi, G. Giammona.
J. of Drug Targeting, 20 (5) 433 (2012)
103) Oxadiazolyl-pyridines and perfluoroalkyl-carboxylic acids as building blocks for protic ionic liquids: crossing
the thin line between ionic and hydrogen bonded materials
Pibiri, I., Pace, A., Buscemi, S., Causin, V., Rastrelli, F., & Saielli, G.
Phys. Chem. Chem. Phys., 2012,14, 14306-14314
104) Sinthesis of Tetrasubstituted 4,4’-Biimidazoles.
A. Martorana, A. Pace, S. Buscemi, A. Palumbo PiccionelloOrganic
Letters, 14 (13) 3240 (2012).
105) Synthesis of Isoxazoline Derivatives through Boulton–Katritzky Rearrangement of 1,2,4-Oxadiazoles
A. Palumbo Piccionello, A. Guarcello, Andrea Pace, and S. Buscemi
Eur. J. Org. Chem., 1986-1992 (2013).
106) Photochemical functionalization of allyl benzoates by C-H insertion
I. Pibiri, A. Palumbo Piccionello, Andrea Pace, G. Barone and S. Buscemi
Tetrahedron, 69, 6065 (2013)
107) Hsp60, a Novel Target for Antitumor Therapy: Structure-Function Features and Prospective Drugs Design
A. Pace, G. Barone, A. Lauria, A. Martorana, A. Palumbo Piccionello, P. Pierro, A. Terenzi, A.M. Almerico, S.
Buscemi, C. Campanella, F. Angileri, F. Carini, G. Zummo, E.C. de Macario, F. Cappello and A.J.L. Macario
Current Pharmaceutical Design, 19, 2757 (2013)
108) Concise asymmetric synthesis of Linezolid through catalyzed Henry reaction
A. Palumbo Piccionello, P. Pierro, A. Accardo, S. Buscemi and A. Pace
RSC Advances, 3, 24946 (2013)
Capitolo libro
1) Synthesis of Heteroaromatics via Rearrangement Reactions.
N. Vivona, S. Buscemi, I. Pibiri, A. Palumbo Piccionello, A. Pace
Albini A,Fagnoni M. HANDBOOK OF SYNTHETIC PHOTOCHEMISTRY. p. 387-416, Wiley-VHC, ISBN:
978-3-527-32391-3
Pubblicazioni scientifiche a carattere divulgativo
1) La benzina “Verde” è verde davvero?
S. Buscemi.
Scienza, Diritto & Economia dell’Ambiente, Anno IV, N. 5/6 (1991)
Conunicazioni a Congressi
1) Studio della reazione di decarbossilazione. Catalisi micellare nella decarbossilazione di alcuni acidi 5-
ammino-1,3,4-ossadiazol-2-carbossilici.
R. Noto, G. Consiglio, F. Buccheri, S. Buscemi, D. Spinelli, e G. Werber.
Società Chimica Italiana – Sezione Sicilia, Convegno Regionale, Palermo (1981).
2) Photorearrangements in the 1,2,4-Oxadiazole System.
N. Vivona, S. Buscemi, M.G. Cicero, and T. Caronna.
“XIIth European Colloquium on Heterocyclic Chemistry” Reims (France) (1986).
3) Fototrasposizione di sistemi 1,2,4-Ossadiazolici.
S. Buscemi, M.G. Cicero e N. Vivona.
Società Chimica Italiana – Sezione Sicilia, Convegno Regionale, Giardini Naxos (1987).
4) Photochemical Behaviour of 1,2,4-oxadiazoles.
S. Buscemi, N. Vivona, and T. Caronna.
“Conference on Photochemistry”, Como (1987).
5) Photoinduced Heterocyclic Rearrangements.
S. Buscemi and N.Vivona.
“Joint meeting RCS and SCI”, Catania (1988).
6) Photochemical behaviour of some 3-Acylamino-1,2,4-oxadiazoles.
S. Buscemi and N. Vivona.
“XIIIth European Colloquium on Heterocyclic Chemistry” Fribourg (Svizzera) (1988).
7) Photochemical Behaviour of 3-Acylamino-1,2,5-oxadiazoles.
S.Buscemi, V. Frenna, T. Caronna, and N. Vivona.
“III Joint Meeting RCS and SCI”, Sciacca (Ag) (1992).
8) Catalisi da ioni metallici nelle trasformazioni eterocicliche. Arilidrazoni di 3-benzoilazoli con Cu(II) acetato
S. Buscemi, V. Frenna, N. Vivona e D. Spinelli;
XXI Convegno Nazionale della Divisione di Chimica Organica della Società Chimica Italiana, Terrasini (Palermo)
(1993).
9) Trasformazioni Eterocicliche. Effetto dei Sostituenti sull’equilibrio “Ring-degenerate” di 3 Acilammino-1,2,4-
ossadiazoli.
S. Buscemi, V. Frenna, N. Vivona e D. Spinelli.
XXI Convegno Nazionale della divisione di Chimica Organica della Società Chimica Italiana, Terrasini (Palermo)
(1993).
10) Riarrangiamenti Molecolari Fotoindotti di 1-Oxa-2-Azoli nella Sintesi di Composti Eterociclici
S. Buscemi, N. Vivona e T. Caronna.
XXIV Convegno Nazionale della divisione di Chimica Organica della Società Chimica Italiana, Monopoli (Bari)
(1996).
11) Riarrangiamenti Molecolari Fotoindotti di 1-Oxa-2-Azoli. Fotochimica di 1,2,4-ossadiazoli in presenza di Tianucleofili:
Sintesi di 1,2,4-Tiadiazoli.
S. Asta, S. Buscemi, N. Vivona e T. Caronna.
Convegno Regionale della Società Chimica Italiana – Sezione Sicilia, Palermo (1997).
12) Riarrangiamenti Molecolari Fotoindotti di 5-Aril-1,2,4-ossadiazoli: Aspetti Meccanicistici nella Formazione di
Chinazolin-4-oni.
S. Buscemi, A. Pace, N. Vivona e T. Caronna.
XXV Convegno Nazionale della Divisione di Chimica Organica della Società Chimica italiana, Folgaria (Trento) (1998).
13) New Polimeric Networks Based on Acryloylated a,b-Poli(N-Hydroxyethyl)-DL-aspartamide.
G. Giammona, G. Pitarresi, G. Cavallaro, and S. Buscemi.
“3rd Interational Symposium on Polymer Therapeutics”, London, U.K. (1998).
14) Photoinduced Singlet Electron Transfer on 5-Aryl-1,2,4-oxadiazoles. Some Mechanistic Investigation in The
Synthesis of Quinazolin-4-ones
S. Buscemi, A. Pace, N. Vivona, T. Caronna, and A. Galia.
“17th International Congress of Heterocyclic Chemistry”, Vienna (1999).
15) Photoinduced Molecular Rearrangements. On the Ring-photoisomerization of 1,2,4-Oxadiazoles into 1,3,4-
Oxadiazoles and Pyrene-Sensitized Photolysis of Some 5-Aryl-1,2,4-oxadiazoles.
S. Buscemi, A. Pace, N. Vivona, and T. Caronna.
“VII joint Meeting on Heterocyclic Chemistry”, Folgaria (Trento) (2000).
16) Fluoroheterocyclic Compounds. A Photochemical Methodology for the Synthesis of 3-Amino- and 3-(NAlkylamino)-5-perfluoroalkyl-1,2,4-oxadiazoles.
S. Buscemi, A. Pace, and N. Vivona.
“VII joint Meeting on Heterocyclic Chemistry”, Folgaria (Trento) (2000).
17) Metodologie Fotochimiche nella Sintesi di Sistemi Eterociclici Fluorurati. Sintesi di 5-Perfluoroalchil- (5-
Perfluorofenil)- 1,2,4-Ossadiazoli
S. Buscemi, A. Pace, N. Vivona.
Convegno Regionale della Società Chimica Italiana – Sezione Sicilia, Palermo (2000).
18) Un Nuovo Processo Fotochimico nella Fotoisomerizzazione del Sistema 1,2,4-ossadiazolico.
S. Buscemi, A. Pace, I. Pibiri e N. Vivona.
XXVIII Convegno Nazionale della Divisione di Chimica Organica della Società Chimica Italiana, Roma (2002).
19) Comportamento Fotochimico di Sostanze Organiche Naturali. Funzionalizzazione Fotoindotta al Metile C-20 del Diterpene Attrattiligenina.
S. Buscemi, S. Rosselli, M. Bruno, N. Vivona e F. Piozzi.
XXVIII Convegno Nazionale della Divisione di Chimica Organica della Società Chimica Italiana, Roma (2002).
20) On the Structure and Reactivity of an Oxadiazole Derivatives in the Study of a Ring degenerate Interconversion.
A. Mugnoli, V. Frenna, M. F. Laganà, S. Buscemi e D. Spinelli.
XXX Convegno Nazionale della Divisione di Chimica Fisica della Società Chimica Italiana, Ferrara (2002).
21) Riarrangiamenti Molecolari nella Sintesi di Sistemi Eterociclici Fluorurati
S. Buscemi, A. Pace, I. Pibiri e N Vivona.
Convegno Regionale della Società Chimica Italiana – Sezione Sicilia, Acireale (Ct) (2002).
22) Crystal Structure of an Oxadiazole Derivative for the Study of a Ring-degenerate Interconversion.
A. Mugnoli, V. Frenna, M. F. Laganà, C. Z. Lanza, S. Buscemi e D. Spinelli.
Convegno della associazione nazionale di cristallografia, Bressanone (2002).
23) Reazioni di Interconversione Isoeterocicliche (Full-degenerate e Ring-degenerate): un Confronto tra Risultati di “InSilicon-Chemistry”
e “Lab-Chemistry”.
S. Buscemi, V. Frenna, M. F. Laganà, C. Z. Lanza, A. Mugnoli e D. Spinelli.
“S.A.Y.C.S.” Riccione (2002).
24) Photochemistry applied to the Synthesis of Fluorinated Heterocycles.
S. Buscemi, A. Pace, I. Pibiri e N Vivona.
Mediterranean Meeting on Photochemistry. Giardini Naxos (Me) (2003)
25) Heterocyclic Rearangements : An Expedient Route on the Synthesis of Fluorinated Heterocyclic Compound.
A. Pace, S. Buscemi, I. Pibiri, N. Vivona, and D. Spinelli.
XIX ICHC Fort Collins, USA (2003)
26) 1,2,4-Ossadiazoli Fluorurati: Sintesi e Reattività Fotochimica.
A. Pace, I. Pibiri, A. Palumbo Piccionello, S. Buscemi e N. Vivona.
Convegno Regionale della Società Chimica Italiana – Sezione Sicilia, Palermo (2003).
27) Fluorinated Heterocyclic Compounds from Ring-to-Ring Transformations of O-N Bond Containing Azoles
A. Pace, I. Pibiri, A. Palumbo Piccionello, S. Buscemi and N. Vivona
“IX joint Meeting on Heterocyclic Chemistry”, Urbino (2004).
28) Sintesi di Composti Eterociclici Fluorurati. Un approccio Fotochimico alla Sintesi di Chinazolin-4-oni.
A. Palumbo Piccionello, A. Pace, I. Pibiri, , S. Buscemi e N. Vivona.
“S.A.Y.C.S.” Riccione (2004).
29) Composti Eterociclici Fluorurati. Sintesi di 2-Ammino-pirimidine N-ossido e 1,2,4-Triazine
A. Palumbo Piccionello, A. Pace e S. Buscemi.
Convegno Regionale della Società Chimica Italiana – Sezione Sicilia, Messina (2004).
30) Fotochimica Organica in Zeolite: dalle Fotoossidazioni ai Riarrangiamenti Eterociclici.
A. Pace, I. Pibiri, A. Palumbo Piccionello, S. Buscemi e N. Vivona.
Convegno Nazionale di Fotochimica – Sirmione (2004)
31) Recent Advances in 1,2,4-Oxadiazole Chemistry.
A. Pace,I. Pibiri, A. Palumbo Piccionello, S. Buscemi and N. Vivona.
20th International Congress on Heterocyclic Chemistry , Palermo (2005).
32) Designing Fluorous Domains. Pyridinium Salts Bearing a Perfluoroalkylated Oxadiazole Moiety.
I. Pibiri, A. Pace, A. Palumbo Piccionello, S. Buscemi and N. Vivona.
20th International Congress on Heterocyclic Chemistry , Palermo (2005).
33) Fluoroarylation of Hydroxylated Molecules with 5-Pentafluorophenyl-1,2,4-Oxadiazoles.
A. Palumbo Piccionello, A. Pace, I. Pibiri, S. Buscemi and N. Vivona.
20th International Congress on Heterocyclic Chemistry , Palermo (2005).
34) Characterization of Isomeric Organic Cations by Esi/MS 3-Alkyl-5-(4-N-Methylpyridinium)-1,2,4-oxadiazole
cations, 5-Alkyl-3-(4-N-Methylpyridinium)-1,2,4-oxadiazole cations and 3-Perfluoroakyil-5-(4-N-Methylpyridinium)-1,2,4-
oxadiazole Cations, 5-Perfluoroakyil-3-(4-N-Methylpyridinium)-1,2,4-oxadiazole Cations,
G. Avellone, D. Bongiorno, S. Buscemi, L. Ceraulo, F. Filizzola, M. Ferrugia, A.Pace, I. Pibiri and N. Vivona.
MASSA 2005 An International Symposium on Mass Spectrometry, Roma (2005)
35) Sintesi “One-pot” di N-Ossidi di 2-Ammino-pirimidine Fluorurate. Riarrangiamenti Competitivi “Four-atom Sidechiam”
di 1,2,4-Ossadiazoli.
A. Palumbo Piccionello, A. Pace, M. Pani, S. Buscemi e N. Vivona
“S.A.Y.C.S.” Riccione (2005).
36) Trasformazioni eterocicliche di 1,2,4-ossadiazoli fluorurati come substrati dielettrofili.
A. Palumbo Piccionello, A. Pace e S. Buscemi.
Convegno Congiunto delle Sezioni Sicilia e Calabria, Catania (2005).
37) Fluorinated Heterocycles from 1,2,4-Oxadiazole Precursors. Synthesis of 3-Amino-Indazoles.
A. Palumbo Piccionello, A. Pace, I. Pibiri, S. Buscemi and N. Vivona
“X Joint Meeting on Heterocyclic Chemistry”, Harrogate, U.K. (2006).
38) ANRORC Rearrangements of Fluorinated 1,2,4-oxadiazoles as an Expedient Route to Fluorinated Heterocycles
S. Buscemi, A. Pace, A. Palumbo Piccionello,I. Pibiri and N. Vivona
“XXII European Colloquium on Heterocyclic Chemistry” – (ECHC)- Bari (2006).
39) Chimica in Fase Gassosa di Ioni Radicali, Cationi e Anioni Prodotti da Ossime di 1,2,4-triazine fluorurate.
G. Giorgi, A. Palumbo Piccionello, A. Pace e S. Buscemi.
XXII Convegno Nazionale Della Società Chimica Italiana, Firenze (2006)
40) A new water-soluble fluorinated polymer based on a polyaspartamide and oxadiazole units as a potential
artificial oxygen (O2) carrier.
D. Mandracchia, G. Pitarresi, G. Giammona, A. Palumbo Piccionello, A. Pace e S. Buscemi.
Simposio Adritelf, Catania (2006).
41) Microreattori Fluorurati. Studio della reazione “Ene” con Ossigeno Singoletto in Zeolite NaY Modificata con
Cationi Fluoroorganici
P. Pierro, A. Pace, S. Buscemi e N. Vivona.
COFEM, Catania (2006)
42) Studio dell’effetto dei sostituenti sul riarrangiamento fotoindotto di diaril-1,2,4-ossadiazoli in zeolite NaY
A. Pace, G. Piscopo, P. Pierro, A. Palumbo Piccionello, I. Pibiri, S. Buscemi, N. Vivona
Sestri Levante – COFEM 2008
42) Trasformazioni Eterocicliche di 1,2,4-ossadiazoli Fluorurati in reazioni ANRORC-Licke
A. Palumbo Piccionello, A. Pace, S. Buscemi e N. Vivona
Convegno Congiunto delle Sezioni Sicilia e Calabria, Rende (2008).
43) Nuovi Riarrangiamenti Boulton-Katritzky di derivati 1,2,4-ossadiazolici contenenti un atomo di carbonio
nucleofilo in catena laterale.
A. Palumbo Piccionello, A. Pace, S. Buscemi e N. Vivona
Società Chimica Italiana Convegno congiunto delle sezioni Calabria e Sicilia. Aci Castello (CT), 1-2 Dicembre 2009
44) Sintesi di ossadiazoli fluorurati come nuovi Low molecular weight hydrogelators.
A. Guarcello, A. Palumbo Piccionello, A. Pace, S. Buscemi e N. Vivona
Convegno congiunto delle sezioni Calabria e Sicilia Società Chimica Italiana. Palermo, 2-3 Dicembre 2010
45) Sintesi di imidazoli e 4,4’-bisimidazoli funzionalizzati tramite reazione di riarrangiamento di isossazoli
A. Martorana, A. Palumbo Piccionello, I. Pibiri, S. Buscemi
Convegno Congiunto delle Sezioni Calabria e Sicilia- Società Chimica Italiana. Palermo, 2-3 Dicembre 2010
46) Novel ANRORC rearrangements of 1,2,4-oxadiazoles.
A. Palumbo Piccionello, A. Pace, A. Guarcello, S. Buscemi e N. Vivona
CONVEGNO NAZIONALE DELLA DIVISIONE DI CHIMICA ORGANICA-SOCIETà CHIMICA ITALIANA. San
Benedetto del Tronto (AP), 12-16 settembre 2010
47) Sintesi di Low Molecular Weight Gelators (LMWG) Fluorurati.
A. Guarcello, Palumbo Piccionello, A. Pace, I. Pibiri, P. Pierro, S. Buscemi
11°Sigma-Aldrich Young Chemists Symposium. Pesaro, 17-19 Ottobre 2011
48) Synthesis of new fluorinated low molecular weight (LMW) gelators
Palumbo Piccionello, A., Guarcello, A., Pace, A., Pibiri, A., & Buscemi, S.
Congresso Nazionale della Società Chimica Italiana, Lecce. 11-16 Settembre 2011
49) Sintesi di nuovi bent-core LC fluorurati
Calabrese, A., Guarcello, A., Palumbo Piccionello, A., Pace, A., & Buscemi, S.
Convegno Congiunto delle Sezioni Sicilia e Calabria. Messina1-2 dicembre 2011
50) Sintesi e valutazione biologica di 1,2,4-ossadiazoli analoghi del Linezolid
Pierro, P., Pace, A., Palumbo Piccionello, A., Pibiri, I., Guarcello, A., & Buscemi, S.
SAYCS Sigma-Aldrich Young Chemists Symposium. Pesaro 17-19 ottobre 2011
51) Synthesis and biological evaluation of 1,4-oxadiazole analogues of Linezolid.
Pirro, P; Palumbo Piccionello, A; Guarcello, A; Buscemi, S; Musumeci, R; Fortuna, CG; Pace, A
Paper presented at RSC-SCI Joint meeting on heterocyclic chemistry, Catania 10-12 Maggio 2012
52) Synthesis of tetrasubstituted-4,4′-biimidazoles with perspective heavy-metal sensing ability
Palumbo Piccionello, A., Martorana, A., Pace, A., & Buscemi, S.
Paper presented at RSC-SCI Joint meeting on heterocyclic chemistry, Catania 10-12 Maggio 2012
53) Synthesis of isoxazoline derivatives by Boulton-Katritzky Rearrangements
Guarcello, A., Palumbo Piccionello, A., Pace, A., & Buscemi, S.
13th RSC-SCI Joint Meeting on Heterocyclic Chemistry. Catania 10-12 Maggio 2012
54) Ionic Self Assembly in the Design of Fluorinated Ionic Liquid Crystals (ILCs).
Pibiri, I., Saielli, G., Causin, V., Palumbo Piccionello, A., Pace, A., & Buscemi, S.
In XXIV Congresso Nazionale della Società Chimica Italiana. Lecce 11-16 Settembre 2012.
55) Synthesis and Characterization of perfluoroalkyl-pyrenes embedded in a polymethylmethacrilate matrix.
Pibiri, I., Buscemi, S., Saladino, M.L., Nasillo, G., & Caponetti, E.
Futurmat 2 – 2nd International Meeting on Organic Materials for a Better Future. Brindisi 16-20 Settembre 2012
56) Synthesis and characterization of a new set of protic ionic liquids
Pibiri, I., Pace, A., Buscemi, S., Inguanta, R., Mistretta, M.C., & Sunseri, C.
Futurmat 2 – 2nd International Meeting on Organic Materials for a Better Future. Brindisi 16-20 Settembre 2012
AMBITI DI RICERCA
L’attività scientifica svolta ha riguardato tipici argomenti di chimica organica ed è stata orientata
prevalentemente verso la chimica dei composti eterociclici. Nelle linee generali, essa è riconducibile a
diversi settori di ricerca caratterizzanti, quali:
Riarrangiamenti Molecolari di Sistemi Eterociclici;
Comportamento Fotochimico di Eterocicli Pentatomici;
Composti Eterociclici Fluorurati.
Foto-funzionalizzazione di composti organici naturali;
Foto-reticolazione di strutture polimeriche per applicazioni farmacologiche.
Sintesi di Nuovi Sistemi Eterociclici Fluorurati per applicazioni avanzate.
Nuovi antibiotici per ceppi batterici antibiotici resistenti
Nuove molecole con potenziali attività anti Alzheimer e per la cura della fibrosi cistica
Sintesi di liquidi ionici e dendrimeri fluorurati contenenti sistemi eterociclici, la sintesi di sensori per cationi
metallici, lo studio di idrogeli per applicazioni farmacologiche.